Base Polymers and Fillers
Although there are three main groups of high-modulus plastics—amorphous thermoplastics, imidized materials and semi-crystalline thermoplastics—only the third one has affordable materials suitable for processing into guide rings, bearings, back-up rings and structural components.
Within semi-crystalline thermoplastics, several base polymers are commonly used in extruded parts for use in off-highway hydraulic systems:
- Polyamide (PA or Nylon)
- Polyphthalamide (PPA)
- Polyetheretherketone (PEEK)
- Polyoxymethyline (POM or acetal)
- Ultra-high-molecular-weight polyethylene (UHMW-PE)
These polymers vary in terms of temperature resistance, tensile strength, flexural modulus (bending stiffness), Izod impact (toughness/resistance to impact) and chemical resistance. For example, PEEK materials are extremely strong and temperature resistant, but UHMW-PE is tough and abrasion resistant.
Several different fillers are used to add strength or modify the tribological effects of these thermoplastics. For example, adding a polytetrafluoroethylene (PTFE) powder to the pellets used in injection molding can reduce friction and improve the wear characteristics of PEEK materials. And adding molybdenum disulfide (moly) to nylon leads to a harder and more wear-resistant surface.
Glass or carbon fibers can be added to thermoplastics to add strength. A common example is adding glass to PA to enhance strength and reduce the amount of water the final product will absorb. Similarly, adding carbon fiber to a PEEK improves wear properties and extend the life of components such as guide rings in high-temperature applications.
Generally speaking, the higher the temperature resistance and strength of one of these thermoplastics, the higher the cost. For example, PEEK materials are extremely strong (operating stress of up to 11,000 PSI) and resist temperatures up to +450ºF. However, this performance comes at a cost. For some applications, the additional cost is worth it; for others, it may make sense to instead use a POM (acetal), UHMW, or a PA with a filler such as glass.